Evaporation (ZLD)

Evaporation like drying, removes volatile substances from a solution but the two processes differ in the following,

• Evaporation
  • Removal of most water from solution
  • Normally takes place at boiling point of water
• Drying
  • Removal of small amount of water from solid material (moisture)
  • Occurs at temperature below boiling point and is typically influenced by humidity

Evaporators include a heat exchanger which task is to boil the solution and they also have a method to separate the vapor from the boiling solution. Evaporator types can be categorized according to their length and the positioning (horizontal or vertical) of the evaporator tubes (Fig.1) which can be inside or outside of the main vessel.

大多数材料不容许temperatu高res so normally evaporators operate at reduced pressure so that the boiling point (BP) is reduced. This means that a vacuum pump or a jet ejector vacuum system on the last effect of the evaporator is required.

Fig.1, Evaporator types. (a) Horizontal-tube, (b) Vertical –tube, (c) Long-tube vertical and (d) Forced circulation

1. Selection of suitable evaporator

Selecting the right evaporator case-by-case is done according to a number of factors, which are,

1. Feed
2. Solution viscosity (and its increase during evaporation)
3. Nature of the product and the solvent (e.g. heat sensitivity and corrosiveness)
4. 污染特征s
5. Foaming characteristics

Evaporator Type	Feed Condition							Suitable for heat sensitive
	Viscosity, cP			Foaming	Scaling or Fouling	Crystals production	Solids in Suspension
	High >1000	Medium 100-1000	Low <100
Calandria (short tube vertical)
Forced Circulation
Falling Film
Natural Circulation
Agitated Film (single pass)
Long Tube Falling Film
Long Tube Raising Film

2. Single-Effect vs. Multiple-Effect

Fig.2, Single and Multiple Effect Evaporators configurations.

There are three criteria that affect performance of an evaporator,

1. Capacity (kg vaporized / time)
2. Economy (kg vaporized / kg steam input)
3. Steam Consumption (kg / hr)

Where Consumption = Capacity / Economy.

Economy (or steam economy) is the kilograms of water vaporized from all the effects (per kilogram of steam used). For single effect evaporator, the steam economy is ca. 0.8 (<1), which translates to 0.8 tons of steam needed to evaporate 1 ton of water.

So as to decrease the evaporator steam economy, the multiple-effect design uses the exhaust vapors from the product to heat the downstream evaporation effect and reduce the steam consumption.

The capacity of a multiple effect evaporator (n effects) is ca. n*single effect evaporator capacity and the economy is about 0.8*n.

Evaporators need also pumps, interconnecting pipes and valves that are required for transfer of liquid from one effect to another effect and they increase both the CAPEX and OPEX of the process.

	Live Steam	Vapor	Steam Economy
1-effect plant	1 kg/h	1 kg/h	100%
3-effect plant	1 kg/h	3 kg/h	33%

Table 1, Decrease of the evaporator steam economy by using a three effect evaporator

Single Effect (SE)

• Small capacity but wasteful energy (1 kg steam vaporize 1 kg water)
• Overall temperature drop for single effect is somewhat equal to multiple effect

Multiple Effect (ME)

• Each individual effect will have a smaller temperature difference, thus high area of heating surfaces
• Capital cost more costly
• Operating cost- steam economy, only required for the first effect (1 kg steam vaporizes 3 kg water)

3. Evaporator Types

The temperature of the feed has an important effect on the evaporator’s economy and performance. If it is not already at its boiling point, then heat effects must take place. If the feed is above the boiling point, flash evaporation is used at the entry.

Normally, the feed solution is heated with a pre-heat exchanger to reduce the evaporation heat demand by transferring heat from the hot condensate to the feed stream.

The heated feed is then mixed with the evaporator liquid and the mixture is heated by the main heat exchanger which can use steam, electricity, hot oil, or other forms of available energy. The mixture boils, producing a concentrated liquid stream and a water vapor stream which can be discharged or condensed.

Vapor compression (VC) evaporation has been the norm ZLD technology for the last decades, recovering ca. 95 % water from the feed. The concentrated liquid stream (brine) can then be driven to a crystallizer in order to be solidified.

蒸发是相当昂贵的,而不是经济ly feasible with large feed flow rates, which is why a pre-concentration step is applied to the ZLD process.

There are different kinds of evaporators,

1. falling film
2. rising film
3. forced circulation
4. scraped surface/thin film
5. combination evaporator

The main ones are,

1. Falling Film Evaporators (FFEs)

FFEs have many energy-saving, multiple-effect evaporation and mechanical vapor re-compression features. A FFE operates with a very small operating temperature and allows,

• easy controls
• fast start up and shut down due to a minimal liquid hold-up

FFEs are chosen for viscous streams with small concentrations of suspended solids. A FFE has small to large flow rates capacity.

1. Forced Circulation Evaporators (FCEs)

Because of the high circulation flow-rate and the evaporation taking place externally to the heat exchanger, FCEs are chosen for highly viscous streams containing a large concentration of suspended solids and fouling contaminants. It has medium to large flow rates capacity.

1. Thin Film Evaporators (TFEs)/ Dryers

TFEs are mostly chosen in order to decrease the water content down to < 5% (crystallization). Like the FFEs, this technology is easy to control and fast to start up and shut down due to a very low liquid hold-up. TFEs are chosen for highly scaling products and highly viscous fluids. It has small to medium flow rates capacity.

Evaporators distillate stream is usually < 10 ppm TDS (Total Dissolved Solids). The most used is the FFE (also called brine concentrator) that can lead the feed concentration up to 300,000 ppm which leads to a boiling point rise (BPR) of the brine and requires either a large heat-transfer area (large CAPEX) or a large heat temperature (large OPEX).

4. Process explanation

Evaporators can treat streams high chlorides concentration and theoretically separate the water from all of the dissolved species producing a stable solid product that can be landfilled and a high-quality distilled water product.

The steps in the evaporation process are (Fig.3),

• chemical addition (feed tank)
• preheating (feed preheater)
• deaeration
• primary evaporation (brine concentrator)

Fig.3,Evaporation processflow diagram and a photo of a real life module.

Steps 1&2;Acid is added to the feed tank to neutralize bicarbonate alkalinity in order for the solution to be preheated in the plate heat exchangers. Antiscalants are also added for preventing scaling in the preheaters with calcium carbonate.

Step 3;The pre-heated stream is degassed using steam from the evaporator (red line in Figure 3) to remove the dissolved carbon dioxide (alkalinity reduction), dissolved oxygen, and any other non-condensable gases in order to reduce the potential for corrosion of the evaporator.

Step 4;Most of the water evaporation takes place inside the brine concentrator vessel which is seeded with calcium sulfate to minimize scaling. The wastewater is typically saturated with calcium sulfate, which will precipitate and form scaling on the evaporator tubes. By using calcium sulfate seed crystals the dissolved calcium sulfate precipitates preferentially on the seed crystals rather than the evaporator tubes.

The process also requires electricity for the mechanical vapor compression (MVC) cycle. As MVC recycles the latent heat of vaporization, the energy input is quite low,in the range of 15 kWh/m³of feedto minimize the size and cost of the vapor separator and compressor, evaporation occurs at atmospheric pressure.

5. Energy saving

Some of the methods applied for minimizing the energy consumption of the evaporation plants include,

• Multiple effect arrangement (ME)
• Thermal vapor recompression (TVR)
• Mechanical vapor recompression (MVR)
• Mechanical vapor compression (MVC)
• Usage of waste energy

For evaporators, the MVC approach is the most widely used.

5.1 Mechanical Vapor Compression

In the MVC evaporator, heat is transferred to the circulating stream by condensing vapor from the compressor(s) (increasing the vapor’s temperature and pressure). In doing so it requires much less energy than a default evaporator.

During process (Fig.4), the vapor generated from the circulating stream has a large amount of energy in the form of latent heat at a temperature of the boiling wastewater. In order for the main heat exchanger to work, a higher temperature will be required. In order to get to the needed higher temperature, the vapor is compressed by the vapor compressor. Compressing the vapor raises its pressure (thus its saturation temperature as well) and produces the needed heat transfer in the main heat exchanger allowing for recycling the energy contained by the vapor, greatly improving the total energy efficiency.

1. Feed wastewater goes from the feed pump to the feedstock heat exchanger and in the circulating stream. The feedstock heat exchanger heats transfers sensible heat from the hot condensate to the cooler feed.

Fig.4, Mechanical Vapor Compression process

2. The recirculation pump circulates wastewater from the separation tank through the main heat exchanger, to the orifice plate, and back into the separation tank. The latent heat from the compressed vapor is transferred to the wastewater via the main heat exchanger.
3. An orifice plate is used to reduce the pressure of the circulating stream. The downstream pressure is low enough to allow flashing of the circulating stream into liquid and vapor components.
4. The liquid and vapor then flow to the separation tank where they are separated. The liquid steam exits the tank at the bottom and flows back to the recirculation pump. The vapor stream exits the tank at the top and flows to the vapor compressor(s).
5. A mist pad is provided at the top of the separation tank to remove small droplets of liquid from the vapor.
6. The vapor compressor compresses the vapor (raising the temperature and pressure), and sends the vapor to the main heat exchanger, where it transfers its latent heat to the wastewater in the recirculation loop.
7. High temperature condensate exits the main heat exchanger and flows to the condensate tank, where any remaining vapor is separated. The hot condensate is then pumped to the feedstock heat exchanger, where it transfers sensible heat to the incoming feed wastewater.
8. Upon reaching steady-state at the target concentration, the concentrated wastewater is purged from the recirculation loop, using the residue valve. Depending on the energy balance, energy can be added to the system by electric heaters / process steam or excess energy can be removed from the system by the steam relief valve.